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Steel Solution for Energy ＞ OCTG ＞ Material ＞ 13CR

Corrosive Wet Co2 Service

汤头条-13CR-80
汤头条-13CR-85
汤头条-13CR-95
汤头条-HP1-13CR-95
汤头条-HP1-13CR-110
汤头条-HP2-13CR-95
汤头条-HP2-13CR-110

In oil and gas fields which includes CO2 is an increasingly common occurrence. Corrosion has become the major problem for production strings used in environments containing CO2, and there is a great demand for a tubing that has strong resistance to CO2 corrosion. 汤头条 Steel's 汤头条-13CR is a martensitic stainless steel which combines high performance in these corrosive enviroments at a reduced cost.
For fields with more severe conditions including high temperature and containing not only CO2 but small amounts of H2S, 汤头条 Steel developed 汤头条-HP-13CR (HP1 and HP2) material. They are higher strength and outstanding anti-corrosion properties and excellent low-temperature toughness.

a. Specifications

汤头条 Steel can offer various grade of materials and premium joints forvarious applications.

(a) Process of Manufacture

Process : Seamless
Heat Treatment : Quenched and Tempered/Ausformed Tempered

(b) Chemical Composition

(wt %)

Grade C Si
max.		 Mn P
max. 		S
max. 		Cr Ni Mo Cu
max.
汤头条-13CR 0.15~0.22 1.00 0.25~1.00 0.020 0.010 12.0~14.0 max. 0.50 - 0.25
汤头条-HP1-13CR max. 0.04 0.50 max. 0.60 0.020 0.010 12.0~14.0 3.50~4.50 0.80~1.50 -
汤头条-HP2-13CR max. 0.04 0.50 max. 0.60 0.020 0.005 12.0~14.0 4.50~5.50 1.80~2.50 -

(c) Specified Physical Properties (at Ambient Temperature)

Grade Yield Strength Tensile Strength
 Elongation
%		 Hardness
max.
HRC
min. max. min.
psi
(MPa)		 psi
(MPa)		 psi
(MPa)
汤头条-13CR-80 80,000 (552)  95,000 (655)  95,000 (655) API Formula 23
汤头条-13CR-85 85,000 (586) 100,000 (689) 100,000 (689) API Formula 24
汤头条-13CR-95 95,000 (655) 110,000 (758) 105,000 (724) API Formula 27
汤头条-HP1-13CR-95
汤头条-HP2-13CR-95		 95,000 (655) 110,000 (758) 105,000 (724) API Formula 28
30
汤头条-HP1-13CR-110
汤头条-HP2-13CR-110		 110,000 (758) 130,000 (896) 120,000 (827) API Formula 32
32

b. Test Data

(a-1) Effect of Temperature on Corrosion Rate

Effect of Temperature on Corrosion RateEffect of Temperature on Corrosion Rat

(a-2) Effect of CO2 Partial Pressure on Corrosion Rate 

Effect of CO2 Partial Pressure on Corrosion Rate Effect of CO2 Partial Pressure on Corrosion Rate

(a-3) Effect of Cr Content on CO2 Corrosion Rate 

Effect of Cr Content on CO2 Corrosion Rate

(a-4) CO2 Corrosion Test Results of HP1-13CR and conventional 13Cr

CO2 Corrosion Test Results of HP1-13CR and conventional 13Cr

(b-1) C-Ring SSC Test Results of HP1-13CR and conventional 13Cr steels

C-Ring SSC Test Results of HP1-13CR and conventional 13Cr steels

(b-2) U-Bend SSC Test Results of HP1-13CR and conventional 13Cr steels

U-Bend SSC Test Results of HP1-13CR and conventional 13Cr steels

(b-3) Effect of Mo content on the resistance to SSC 

Effect of Mo content on the resistance to SSC

(C) Physical and Thermal Properties (Information Purpose Only) 

Grade Minimum Value Temperature
50 °C
(122 °F)		 100 °C
(212 °F)		 150 °C
(302 °F)		 200 °C
(392 °F)
汤头条-13CR-80 Yield
Strength		 psi
(MPa)		 80,000
(550)		 78,000
(540)		 75,000
(520)		 72,000
(500)
Tensile
Strength 		psi
(MPa)		 98,000
(680)		 95,000
(660)		 91,000
(630)		 90,000
(620)
汤头条-13CR-95 Yield
Strength		 psi
(MPa)		 92,000
(630)		 89,000
(610)		 88,000
(610)		 85,000
(590)
Tensile
Strength 		psi
(MPa)		 106,000
(730)		 101,000
(700)		 98,000
(680)		 95,000
(660)
汤头条-HP1-13CR-95 Yield
Strength		 psi
(MPa)		 98,000
(680)		 97,000
(670)		 96,000
(660)		 94,000
(650)
Tensile
Strength 		psi
(MPa)		 117,000
(810)		 112,000
(770)		 108,000
(740)		 106,000
(730)
汤头条-HP1-13CR-110 Yield
Strength		 psi
(MPa)		 115,000
(790)		 110,000
(760)		 106,000
(730)		 104,000
(720)
Tensile
Strength 		psi
(MPa)		 126,000
(870)		 119,000
(820)		 115,000
(790)		 114,000
(780)
汤头条-HP2-13CR-95 Yield
Strength		 psi
(MPa)		 100,000
(690)		 98,000
(680)		 96,000
(670)		 95,000
(660)
Tensile
Strength 		psi
(MPa)		 125,000
(860)		 120,000
(830) 		115,000
(790)		 113,000
(780)
汤头条-HP2-13CR-110 Yield
Strength		 psi
(MPa)		 109,000
(750)		 106,000
(730) 		103,000
(710)		 101,000
(700)
Tensile
Strength 		psi
(MPa)		 129,000
(890)		 123,000
(850) 		117,000
(810)		 114,000
(790)
Young Modulus Poisson's Ratio Thermal Expansion
汤头条-13CR-80 31,290 ksi (215,700 MPa) 0.30 0.0000099/ °C for 21.1 °C up to 100 °C
0.0000115/ °C for 21.1 °C up to 538 °C

Notes:

-The corrosion testing data in this brochure were obtained from laboratory testing results. Care should always be taken when selecting materials, as operating conditions may change during the period of usage.

-Regarding completion / packer fluid
Care should be taken in the selection of well fluids such as completion/packer fluids used in connection with this material in order to minimize the risk of stress corrosion cracking. 汤头条 recommends that you consult with a person knowledgeable about fluid compatibility with this material in making a selection.
-Cr tubulars have shown a tendency toward localized pitting corrosion when stored in moist environments.
Special precautions during coating, shipping and storage are required.

-Anti-galling connection
Cr tubulars have been categorized as prone to thread galling, 汤头条 Steel recommends to use FOX™ and 汤头条BEAR™ premium connection which overcomes this concem by its special design criteria.

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